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WOLFRAM NOTEBOOK
The Seven Crystal Classes
The Seven Crystal Classes
The three-dimensional arrangement of the atoms, molecules, or ions in a crystalline solid can be described by the geometry of its unit cell. The entire crystal can then be constructed by translational repetitions of the unit cell. A unit cell is described by six lattice parameters: edge dimensions ,, and inter-edge angles , , . There are seven possible crystal systems that can produce an infinite lattice in three-dimensional space so that each lattice point has an identical environment. Depending on relationships between lattice parameters, the seven crystal systems are classified as cubic (or isometric), tetragonal, orthorhombic, rhombohedral (or trigonal), hexagonal, monoclinic, and triclinic. (This Demonstration does not consider further classifications within these crystal systems, such as body-centered, face-centered, etc., which make up a total of 14 Bravais lattices.)
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The values for the six lattice parameters automatically determine the crystal class, which you can display either as a parallelepiped in the shape of the unit cell or as a segment of the crystal lattice. Different atomic radii can be simulated by reducing the dimensions ,, by the same proportions.
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Rotation of the crystal lattice can display some of its symmetry elements. For example, you can rotate the cubic crystal shown in the Thumbnail to show that it has four distinct three-fold axes of symmetry.