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Simple Batch Distillation of an Ethanol-Water Mixture

pressure in mmHg
760
temperature profile
composition profile
An equimolar binary mixture of ethanol and water is to be separated in a still pot, which initially contains 0.575 kmol of the mixture. You can set the operating pressure,
P
, of this simple batch distillation experiment, where
P
can vary from 700 to 900 mmHg so that the ideal gas-phase assumption holds.
This Demonstration plots the temperature of the liquid in the still,
T
S
, and the temperature of the distillate (i.e., condensed vapor exiting from the still),
T
D
, versus time (green and magenta curves, respectively). As expected,
T
D
lags behind
T
S
because the distillate is richer in ethanol.
In addition, you can see the plots of the composition in the still,
x
S
, and in the distillate,
x
D
. For this transient problem, computations include both the mass and the energy balance equations. For higher total pressure values, the temperature profiles are shifted to higher values. A constant-heating policy of the still pot is used with
q
2.125kW
.
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