Quasi-Reversible and Irreversible Voltammograms at Microelectrodes
Quasi-Reversible and Irreversible Voltammograms at Microelectrodes
When the kinetics of the reaction occuring in cyclic voltammetry is limited, the shape of the voltammogram depends strongly on the kinetic parameter: the standard rate constant . This Demonstration shows a simulation of cyclic voltammetry with a microelectrode in steady state and under quasi-reversible and irreversible kinetics.
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