WOLFRAM|DEMONSTRATIONS PROJECT

Eigenvalues and Eigenfunctions for the Harmonic Oscillator with Quartic, Sextic and Octic Perturbations

​
perturbation exponent β
4
6
8
perturbation prefactor α
0.1
quantum number n
0
ψ
n
&
(0)
ψ
n
Δψ
V(x)
ψ
n
(0)
ψ
n
This Demonstration calculates eigenvalues and eigenfunctions for the perturbed Schrödinger equation
-
2
ℏ
2m
2

ψ

2
x
+(V(x)-E)ψ=0
with
V(x)=
(0)
V
(x)+α
β
x
, where
(0)
V
(x)=
1
2
2
ω
2
x
. Units are
ℏ=m=ω=1
. The energies and wavefunctions for the unperturbed potential
(0)
V
(x)
are given by
(0)
E
=n+
1
2
and
(0)
ψ
(x)=
-
2
x
2

H
n
(x)
1/4
π
n
2
n!
, where
H
n
(x)
is a Hermite polynomial. When you select "
ψ&
(0)
ψ
", the numerical solution for
ψ(x)
and the unperturbed solution
(0)
ψ
(x)
are plotted. When you select "
Δψ
",
ψ(x)-
(0)
ψ
(x)
is plotted. When you select "
V(x)
",
V(x)
is shown as a solid black line,
(0)
V
(x)
as a dashed red curve and
ψ(x)
as a blue curve. The unperturbed eigenvalue is given by
E
n
=n+
1
2
in all cases.