WOLFRAM|DEMONSTRATIONS PROJECT

Carnot Cycles with Irreversible Heat Transfer

​
heat engine
heat pump
|
T
h
-
T
H

10
|
T
c
-
T
C

12
This Demonstration shows a Carnot cycle operating either as a heat engine or a heat pump, with finite temperature differences between the hot and cold reservoirs and the high and low temperatures of the Carnot cycle, respectively. The entropy changes for the reservoirs (
Δ
S
h
and
Δ
S
c
) and the overall entropy change
Δ
S
total
are calculated. When the temperature differences between the reservoirs and the engine/pump are nonzero, the total entropy change is positive. The entropy change of the engine/pump, which is at steady state, is zero. All energies and entropy changes are per unit time, since these are continuous processes, but the time scale is arbitrary. The cycle efficiency
η
is calculated for the heat engine, and the coefficient of performance (
COP
) is calculated for the heat pump. As the temperature difference between the reservoirs and the engine/pump increases, the efficiency and the coefficient of performance decrease. For the heat engine,
Q
H
is held constant as the temperature differences change. For the heat pump,
Q
C
is held constant as the temperature differences change.